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Опубликовано 2011-03-31 Опубликовано на SciPeople2011-03-31 08:10:31 ЖурналPhysica B

Facile synthesis of thiol-stabilized CdSeTe nanocrystals
R. Sathyamoorthy, P. Sudhagar, R. Saravana Kumar, P. Matheswaran, Ranjith G. Nair / Nair Ranjith
Аннотация CdSexTe1x nanocrystals (x¼0.25, 0.40, 0.50, 0.60 and 0.75) were synthesized using thioglycerol as a stabilizing agent. The composition of the CdSexTe1x nanocrystals was precisely controlled by tuning the precursor (Se/Te) ratio. The structural, morphological and optical properties of the nanocrystals were analyzed using X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), diffused reflectance spectroscopy (DRS) and photoluminescence (PL) measurements. It is found that the Se/Te ratio significantly affects the properties of the resultant CdSexTe1x nanocrystals. XRD pattern of the CdSexTe1x nanocrystals revealed cubic, hexagonal and mixed phases depending on the ratio of Se:Te. Surface morphology of the CdSexTe1x nanocrystals showed nanoclusters of sizes 50 nm, with the adjacent cluster interlinking each other. DRS revealed the size dependence band gap energy prevailing in the CdSexTe1x nanocrystals from1.52 to 2.66 eV due to the optical bowing effect. PL measurements exhibited band edge emission in the visible spectral region, and are red shifted with increase in Se concentration. The facile route employed in the present work to synthesis the CdSexTe1x nanocrystals in an aqueousmediumis simple and controllable, and the strategy presented will be handy in preparing diverse semiconducting nanocrystals


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