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Опубликовано 2014-12-13 Опубликовано на SciPeople2014-12-13 10:38:25 ЖурналRSC Advances (2014), 4, 6597-6601.

Magnetically retrievable MFe2O4 spinel (M = Mn, Co, Cu, Ni, Zn) catalysts for oxidation of benzylic alcohols to carbonyls
Anand S. Burange, Sandip R. Kale, Radek Zboril, Manoj B. Gawande* and Radha V. Jayaram* / Dr. anand Burange
Аннотация The catalytic activity of theMFe2O4 spinel (M ¼ Mn, Co, Cu, Ni, Zn) was investigated for the oxidation of benzylic alcohols to respective carbonyls using tert-butyl hydroperoxide (TBHP) as an oxidant. The combination of CoFe2O4/TBHP in a dimethyl sulfoxide (DMSO) catalytic system was found to be most efficient for this catalytic conversion. A CoFe2O4 catalyst is magnetically separable and could be reusedwith no considerable loss in catalytic activity as proved for 5 consecutive cycles.
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