Dr. anand Burange » Публикация
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Опубликовано
2014-12-13
Опубликовано на SciPeople2014-12-13 10:38:25
ЖурналRSC Advances (2014), 4, 6597-6601.
Magnetically retrievable MFe2O4 spinel (M = Mn, Co, Cu, Ni, Zn) catalysts for oxidation of benzylic alcohols to carbonyls
Аннотация
The catalytic activity of theMFe2O4 spinel (M ¼ Mn, Co, Cu, Ni, Zn) was
investigated for the oxidation of benzylic alcohols to respective
carbonyls using tert-butyl hydroperoxide (TBHP) as an oxidant. The
combination of CoFe2O4/TBHP in a dimethyl sulfoxide (DMSO) catalytic
system was found to be most efficient for this catalytic conversion.
A CoFe2O4 catalyst is magnetically separable and could be reusedwith
no considerable loss in catalytic activity as proved for 5 consecutive
cycles.