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Аннотация The model, which describes internal motion of ions within the cluster formed by hydrated ions of different signs, is suggested in this work. The contribution of the ions motion into the electroconductivity of atmosphere contained these ion-water complexes is computed by the methods of molecular dynamics. It is shown that the contribution of such kind of clusters is comparable with that of individual hydrated clusters H+(H2O)n. The agreement of results of modeling with a theory of linear response is satisfactory for high frequences of external field