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Опубликовано 2007-05-01 Опубликовано на SciPeople2009-12-05 20:28:44 ЖурналOrganic & Biomolecular Chemistry

Oxidation of some cage hydrocarbons by dioxiranes. Nature of the transition structure for the reaction of C-H bonds with dimethyldioxirane: A comparison of B3PW91 density functional theory with experiment.
S. A. Grabovskiy, A. V. Antipin, E. V. Ivanova, V. A. Dokichev, Yu. V. Tomilov, N. N. Kabal’nova / Станислав Грабовский
2007, V.5, No.14, 2302 – 2310
Аннотация Dimethyl- (DMD) and methyl(trifluoromethyl)-dioxiranes were used for oxyfunctionalization of spiro{1',7-cyclopropan-2-(E)-methyl-bicyclo[2.2.1]heptane} (1), tricyclo[,4)]nonane (2), exo-endo-endo- (3) and exo-exo-exo-heptacyclo¬[,10).0(3,8).0(4,6).0(5,9).0(12,14)]pentadecane (4), yielding tertiary alcohols as the main products. The rate constants for oxidation of 1-4 by DMD were measured and the Arrhenius parameters determined. The DFT theory (B3LYP and B3PW91) using restricted and unrestricted methods was employed to study the oxidation reaction of the C–H bond of cage hydrocarbons 1-4, adamantane, and acetone with DMD. The kinetic isotopic effect calculated using unrestricted methods agree with experiment. The reaction mechanism in terms of the concerted oxygen insertion vs the radical part is discussed.


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